Question - Why can @import be at the top only?
Answer -
A style sheet that is imported into another one has a lower ranking in the cascading order: the importing style sheet overrides the imported one. Programmers may recognize this as the same model as in Java, Modula, Object-Pascal, Oberon and other modular programming languages.
However, there is a competing model, well-known to C programmers, where the imported material is not lower in rank, but is expanded in-place and becomes an integral part of the importing document.
By allowing @import only at the top of the style sheet, people that think in terms of the second model (although in principle incorrect) will still get the expected results: as long as the @import is before any other overriding rules, the two models are equivalent.
Btw. In all the modular languages import statements are only allowed at the top. In C, the #include can be put elsewhere, but in practice everybody always puts it at the top. So there may not be that much need to allow @import elsewhere in the style sheet either.